Not sure, it works here with this simple test of psexec on a remote WinXP machine located on a different NT domain.
Attached is the build file and the test script I ran with it. [You'll have to change the computername, user and password values from *** to run it]
A reproduceable case would be helpful for troubleshooting. I can only guess that it is some sort of rights issue, but I certainly don't know for sure...
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